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CONCEPTS
- Solids, liquids and gases expand when heated.
- Water expands about four percent when heated from room temperature
to the boiling point.
- The ocean will expand when heated.
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MATERIALS
- Empty 750 milliliter bottles (e.g., a clear wine bottle) or beaker
with a thin neck
- 0 - 100°C thermometers
- Gas burners with stands or electric hot plates
- Metric rulers
- Six-inch cooking pans (or pots)
- String or emory boards
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PREPARATION
- Depending on what is available, heating the water can be done at school
by using Bunsen burners, a hot plate, or a propane camp unit. At home,
a kitchen stove is suitable. Place the bottle or beaker in a cooking
pan with water to reduce the possibilty of breaking the bottle. Use
pyrex instead of a glass bottle if you have a suitable container with
a thin neck (such as pyrex Florence flasks). A thin neck will allow
ease of measuring changes, because the height of the water will increase
more for an equivalent change in volume. In any case, use great care
around the bottle, wearing protective eyewear if possible. The thermometer
can be suspended in the heated water using string or an emory board
with a small hole punched through it. Test a method for suspending the
thermometer before doing the activity in class. For safety, do not let
the water reach boiling temperature (100°C).
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PROCEDURE
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Engagement
- Small changes in Earth's global average temperature can produce
dramatic changes in climate. Scientists are trying to determine
how much Earth's mean temperature is changing. One way to do this
is to monitor sea level. Warming results in higher sea levels,
which may strongly affect the population who live near the ocean.
There is geologic evidence for very large variations in Earth's
sea level in the past. There are two main causes of these sea
level changes: (1) thermal expansion or contraction of the existing
ocean water, and (2) changing volume of water due to the melting
or freezing of polar ice caps and glaciers. Changes in the climate
affect both of these.
- Over the past hundred years, sea level averages have risen 15
cm (6 in) for about 0.5°Celsius degree (0.9°F) of average
global temperature increase. Some computer models predict that
a doubling of the present carbon dioxide level in the atmosphere
of 0.032% over the next hundred years would increase ocean waters
by 3°C (5.4°F). Using the 15 cm/0.5°C above, this
would cause a sea level rise of about one meter (3.3 ft).
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Activity
- Mark the point on the bottle that is 7 cm from the top. Optionally,
measure the inside and outside diameters of the bottle at the
top and and at 7 cm below the top to determine the dimensions.
For example, for a sample 750 ml wine bottle, the measured top
and 7 cm position outside diameters were 2.4 cm and 3.0 cm respectively.
The corresponding inside diameters were 1.8 cm and 2.4 cm (assuming
constant thickness).
- Fill the 750-ml bottle with water to just below the bottom of
the neck. Ice can be used to bring the temperature down to 20°C
if desired.
- Support the thermometer in the bottle so that the bulb is well
below the neck in the main body of water. Use either string or
something similar to an emory board placed horizontally on the
bottle top with the thermometer suspended through it.
- Add or pour out water so that with the thermometer in the bottle,
the water level is 7 cm below the top, as measured with the ruler
held vertically.
- Fill the cooking pan about two-thirds full of water and place
on the heat source.
- Center the bottle in the pan. The water level in the pan should
be at least three cm below the top.
- Heat the water to at least 80°C while recording the water
level every 5 or 10°C in Table 1. To
prevent the water from spilling, turn off the heat source if the
water in the bottle reaches to within one cm of the top. Graph
height versus temperature and the change in height versus temperature.
Does the height change more or less rapidly at higher water temperatures?
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Explanation
- Most materials expand on heating, although some contract over
limited ranges of temperature. On average, liquids expand about
ten times as much as solids, and gases expand much, much more
than liquids. The correction for the expansion of the solid bottle
was not included here because it will be very small compared to
the expansion of the water. Note that the expansion for water
is much greater near its boiling point than near room temperature.
- When oceans heat up, they expand as well, causing a rise in
sea level. This, along with melting and freezing of water in glaciers
and polar caps, has caused large variations in sea level in Earth's
past as the average global temperature changed. Such changes could
occur in the future as well. What you constructed in this activity
was basically a thermometer. If you had calibrated the expansion
versus temperature in this experiment, then you could determine
temperature by measuring the height of the water. However, water
is not very suitable for use in a thermometer for many reasons:
its amount of expansion changes greatly with temperature range,
it evaporates easily, and it does not expand as much as some other
liquids. Most thermometers use mercury because it expands quite
a lot, and does so uniformly over a very large range of temperatures.
(Interestingly, the first thermometer constructed did, in fact,
use water.)
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EXTENSION
- Calculate the volume change of the water that corresponds to the measured
changes in height. This will require a good knowledge of the inner diameter
of the bottle and its variations. For reference, the expected volume
change from 20°C to 90°C is approximately 3.4%.
- You may wish to investigate the expansion properties of other liquids
like mercury and alcohol, both used in thermometers.
- There are many examples of solids that expand with temperature, such
as concrete dividers in sidewalks and bridges. The Golden Gate bridge
is about 0.9 meters (3 feet) longer in summer than in winter, so room
is left on the roadway for expansion to prevent buckling. Can you students
think of other examples of volume changes in solid materials that are
temperature dependent? Have they experienced changes in the way mechanical
devices work during different seasons? Is temperature the only factor
that may be affecting the performance of these devices?
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VOCABULARY
- global warming: increase in average global temperature. Some
of the increases are due to build-up of gases such as CO2
, NO2, and chlorofluorocarbons in the atmosphere
as a result of industrialization.
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SOURCE
- "Visit to an Ocean Planet" educational CD-ROM, Copyright
Caltech and NASA/Jet Propulsion Laboratory
- Adapted from the Orange County Marine / San Juan Institute Series,
San Juan Capistrano, CA.
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